There isn't a bolt on 'true-dual' exhaust system for the 4th gen Explorer for either engine...at least not one that I could find.
It can be done, but not that easily because of the way the chassis/drivetrain is laid out, and your pipe bender will need a lot of time and patience.
A 2.25" system would be easier to fabricate, as far as room...a 2.5" system can be done, but fitting the pipes going over the axle is tight and would need to either be 2.25" in that spot (like mine) or pay 'special' attention to the 2.5" pipes to make them fit.
Unless you have a friend with access to a pipe bending machine, be prepared to spend some cash.