Thanks guys, I was a little worried about what it would look like but the "totally different" look is what I wanted. All I did was tape off the areas I didn't want painted and the wiped the rim down with a Dupli-color prep wipe. It took all the grease and nasty stuff off of it. The paint stuck great. I used Dupli-color High performance wheel coating for the paint. It worked really good and it only took one can of the stuff to do all for wheels. Thanks for all the replies!!!!
Nick