If you haven't already done the fluid change, I'd highly suggest using 75w140 instead of 90. Use a quality full synthetic oil like you mentioned.
I've been talking with a guy who specializes in 4x4 drivelines, and he told me that every one that he rebuilds gets 75w140 synthetic gear oil. He saw no point other than cost savings as to why the manufacturers use 140 weight in the rear, but conventional non-synthetic 80w90 oil in the front. Or we thought it might be for warranty issues...Since the rear end works harder usually, it'd be more prone to failure, so a better quality lube was used, but deemed unnecessary in the front.
All I know is he has never had a lube related failure after switching the front diff out to 75w140 synthetic.
That's what mine's gonna get when I do them. I already have my Schaeffer's 75w140 sitting on the shelf waiting for me to get motivated.