My opinion is differs by 180 degrees.
I'm not drinking the Kool-Aid.
After driving both, I felt the 2.3l to be weak unless under full boost. I've owned several turbo charged engines, and I can't stand the lag. The 2.3l has plenty of it. It's small, too small and peaky for a vehicle of this size, and very laggy in urban driving conditions.
The 3.5 na is much smoother, and more importantly, has a much higher tow rating, and that's all in need to know.
I imagine on flat land, driven at a constant speed, in low boost conditions, it may deliver I-4 economy, but I imagine when all is said and done, the V-6 will deliver the same fuel cost during ownership, without all of the side effects of turbo charging a very small engine.
Least important, I can't stand the buzzing sound of the four banger under the hood of a larger SUV like the Explorer.
Again, JMHO.