I would try to identify what that substance is, and I don't see any mention of the fuel filter being replaced. I wonder if the whole fuel system is gunked up, would replace the filter and if no remedy, put some fuel injector cleaner in the gas and drive it around a while while I contemplated whether to try cleaning or replacing the injectors.
Being cheap, at some point I might pull the spark plugs to see if any look different so if it came to replacing injectors, I started with one (if only one plug looks off). The curious thing to me is that you're not getting any O2 or misfire related trouble codes. Does the oil smell like gas?