Doubt it is fuel temperature related. Your returnless system actually imparts no heat to the fuel in the tank, unlike a return system, keeping fuel tank temperatures cooler than in earlier models. A return system slowly heats the fuel in the tank as excess pressure from the hot rail is returned to the tank.
That, and the fuel in the tank is only subject to convection from the ambient air. There is no direct conduction or radiation. Even on a hot day, your fuel will stay relatively cool.
Really the only possible location you could be experiencing vapor lock would be in the engine compartment, and fuel rail pressure is in excess of 60psi, which decreases fuel volatility. If you told me it was hard to start after shutting down, after heat soaking the stagnant fuel in the feed line, vapor lock would be more likely. If it is running, then starts to stall/run rough, it isn’t vapor lock.
There are members here who drive their Explorers in much hotter climates (Kuwait, off the top of my head). My truck even spent some time in some HOT parts of Texas, with a return system, nonetheless.
Recommend you check fuel pressure, as well as your ignition system. I’ve seen cracked coils get wonky when hot.