FWIW, I have run into this problem before and tried hot water, inclined running with the engine running[real popular on 5.0 liter Mustangs], different thermostats, etc.. The relatively painless fix was to heat cycle the engine with the coolant overflow bottle almost full... Run the engine with the heater on until it got to 190-200 F then shut it down and let it cool for 20-30 minutes..
Especially after changing the coolant and thermostat, I would do this and then pick up tools or clean the engine.. Something to pass the time.. From what I can remember the engine would burp itself and the coolant level in the overflow bottle would drop some and I never worried about it again..
If the coolant level didn't drop, I would heat the engine again and then let it cool down.. I never had to do this more than twice on a properly functioning engine...And I think that is what the engine would do itself over time with a working overflow bottle and closed cooling system...
Now if the head gasket or cylinder head was cracked this story had a different ending....